Pseudo First Order Reactions

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Pseudo First Order Reactions: Overview

This Topic covers sub-topics such as Pseudo First Order Reactions

Important Questions on Pseudo First Order Reactions

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H+ catalysed hydrolysis of ester CH3COOC2H5+H2O     H+        CH3COOH+C2H5OH is a pseudo unimolecular reaction. Explain.

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What are pseudo unimolecular reactions? Explain with the help of a suitable example.

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What is pseudo first order reaction? Give an example of it. 

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Why hydrolysis of ethyl acetate with NaOH is reaction of second order while with HCl, it is of first order?

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State any one condition under which a bimolecular reaction may be kinetically of first order.

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For a reaction, A+H2O            BrateA. What is its order of reaction?
 

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For a reaction A+BP, the rate is given by Rate =k[ A][B]2.

What is the overall order of reaction if A is present in large excess ?

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For a reaction, A+H2O            BrateA. What is its molecularity?
 

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The rate constant for a second order reaction is k=2.303ta-blogba-xab-x where a and b are initial concentrations of the two reactants A and B involved. If one of the reactants is present in excess, it becomes pseudo unimolecular. Explain how?

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In the hydrolysis of an ester in presence of large excess of water. The order of the reaction is 

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For the hydrolysis of esters in alkaline medium rate expression is :-d[Ester]dt= K[Ester][Alkali] In case alkali used is in excess, then the overall order of the reaction is :

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The acid catalyzed iodination of propanone represented by equation :

CH3COCH3+I2H+CH3COCH2I+HI

is first order w.r.t. H+ ion and to propanone and zero order w.r.t. I2. Then correct graph between rate of reaction [R] vs [CH COCH33

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What is pseudo-first order reaction? Give one example.

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Which equation represents the equilibrium condition in the two-sector model?

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Which component of aggregate demand is most likely to be influenced by changes in interest rates?

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In an open economy, which component of aggregate demand accounts for goods and services sold to other countries?

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Which component of aggregate demand includes spending on capital goods?

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Which component of aggregate demand represents the total spending by households?

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What are the components of aggregate demand in a two-sector economy?

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How is Nominal GDP different from Real GDP?